Chemistry Reference
In-Depth Information
O
PPh
2
0.1 mol %
Ni
Cl
O
PPh
2
S
PhI
+
RSSR
Ph
R
1 equiv Zn, DMF
R
Yield (%)
CH
3
99
i
-C
3
H
7
99
n
-C
4
H
9
99
s
-C
4
H
9
99
t
-C
4
H
9
49
C
6
H
5
86
Scheme 6.20
Bn
N
3mol%
Ni
N
Bn
2
S
ArBr
+
PhSH
Ar
Ph
KO
t
Bu, DMF
Ar
Yield (%)
C
6
H
5
99
p
-CH
3
C
6
H
4
94
m
-CH
3
C
6
H
4
93
o
-CH
3
C
6
H
4
80
p
-CH
3
OC
6
H
4
89
p
-(CH
3
)
2
NC
6
H
4
90
Scheme 6.21
15 mol % Ni(COD)
2
H
3
CO
OCH
3
30 mol %
N
N
S
ArX +
[N(CH
3
)
4
][SCF
3
]
Ar
CF
3
THF
Ar
X
Yield (%)
p
-CH
3
C
6
H
4
I
90
1,1
′
-Biphenyl
I
92
p
-EtO
2
C
6
H
4
I
45
C
6
H
5
Br
65
m
-CH
3
C
6
H
4
Br
37
C
6
H
5
Cl
0
Scheme 6.22
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