Advances in C–C and C–X Coupling Using Palladium–NHeterocyclic Carbene (Pd–NHC) Complexes - New Trends in Cross-Coupling: Theory and Applications - page 176

[Pd(IPr)(Im)Cl 2 ](16a 16a)

Cl Si(OMe) 3

R

(1 mol%)

+

R R'

TBAF.3H 2 O
Toluene, 120 - 130°C, 3 h

NN

R'

MeOOC MeO

Cl Pd Cl

NC

N

89% 70% 68%

N

O 2 N Me OC OMe

[Pd(IPr)(Im)Cl 2 ]
16a

N

84% 64% 59%

Scheme 4.32 Reactivity of [Pd(IPr)(Im)Cl 2 ](16a) in Hiyama coupling.