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140. (a) J. P. Wolfe, Eur. J. Org. Chem., 2007, 2007, 571; (b) J. P. Wolfe, Synlett,
2008, 2913.
141. A. Takemiya and J. F. Hartwig, J. Am. Chem. Soc., 2006, 128, 14800.
142. The common names were later reported with the family of
biarylphosphines developed by Buchwald and co-workers.
143. D. W. Old, J. P. Wolfe and S. L. Buchwald, J. Am. Chem. Soc., 1998,
120, 9722.
144. J.-F. Marcoux, S. Wagaw and S. L. Buchwald, J. Org. Chem., 1997,
62, 1568.
145. T. Hayashi, T. Mise, M. Fukushima, M. Kagotani, N. Nagashima,
Y. Hamada, A. Matsumoto, S. Kawakami, M. Konishi, K. Yamamoto
and M. Kumada, Bull. Chem. Soc. Jpn., 1980, 53, 1138.
146. (a) J. P. Wolfe and S. L. Buchwald, Angew. Chem. Int. Ed., 1999, 38, 2413;
(b) J. P. Wolfe, R. A. Singer, B. H. Yang and S. L. Buchwald, J. Am. Chem.
Soc., 1999, 121, 9550.
147. J. P. Wolfe, H. Tomori, J. P. Sadighi, J. Yin and S. L. Buchwald, J. Org.
Chem., 2000, 65, 1158.
148. A. Aranyos, D. W. Old, A. Kiyomori, J. P. Wolfe, J. P. Sadighi and
S. L. Buchwald, J. Am. Chem. Soc., 1999, 121, 4369.
149. (a) H. Ossor, M. Pfeffer, J. T. B. H. Jastrzebski and C. H. Stam, Inorg.
Chem., 1987, 26, 1169; (b) L. R. Falvello, J. Forni´s, R. Navarro, V. Sicilia
and M. Tom´s, Angew. Chem. Int. Ed. Engl., 1990, 29, 891; (c) C.-S. Li,
C.-H. Cheng, F.-L. Liao and S.-L. Wang, J. Chem. Soc., Chem. Commun.,
1991, 710; (d) S. Kannan, A. J. James and P. R. Sharp, J. Am. Chem. Soc.,
1998, 120, 215.
150. The air stability of dialkylbiarylphosphines has since been studied
in detail: T. E. Barder and S. L. Buchwald, J. Am. Chem. Soc., 2007,
129, 5096.
151. J. M. Fox, X. Huang, A. Chie and S. L. Buchwald, J. Am. Chem. Soc.,
2000, 122, 1360.
152. S. Vyskoˇil, M. Smrˇina, V. Hanuˆ, M. Pol´ˆek and P. Koˇovsk´, J. Org.
Chem., 1998, 63, 7738.
153. Y. Uozumi and T. Hayashi, J. Am. Chem. Soc., 1991, 113, 9887.
154. P. Koˇovsk´, S. Vyskoˇil, I. C´saˇov´, J. Sejbal, I. Tiˆlerov´,M.Smrˇina,
G. C. Lloyd-Jones, S. C. Stephen, C. P. Butts, M. Murray and V. Langer,
J. Am. Chem. Soc., 1999, 121, 7714.
155. H. Tomori, J. M. Fox and S. L. Buchwald, J. Org. Chem., 2000, 65, 5334.
156. Improvements have been made to the benzyne synthesis of bi-
arylphosphines since the initial report, see: (a) S. Kaye, J. M. Fox,
F. A. Hicks and S. L. Buchwald, Adv. Synth. Catal.,343, 789;
(b) N. Hoshiya and S. L. Buchwald, Adv. Synth. Catal., 2012, 354, 2031.
157. Recent examples: (a) D. Maiti, B. P. Fors, J. L. Henderson, Y. Nakamura
and S. L. Buchwald, Chem. Sci., 2011, 2, 57; (b) B. P. Fors and
S. L. Buchwald, J. Am. Chem. Soc., 2010, 132, 15914; (c) J. L. Henderson
and S. L. Buchwald, Org. Lett., 2010, 12, 4442; (d) J. L. Henderson,
S. M. McDermott and S. L. Buchwald, Org. Lett., 2010, 12, 4438;
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