Chemistry Reference
In-Depth Information
Carbon-Centered Radicals
6.1
General Remarks
103
6.2
p
K
a
Values of Radicals
103
6.3
Oxidation of Carbon-Centered Radicals
107
6.4
Reduction of Carbon-Centered Radicals
by Electron Transfer
110
6.5
H-Transfer Reactions
111
6.6
Conversion of Reducing Radicals
into Oxidizing Ones (Umpolung)
114
6.7
Reactions with Hydrogen Peroxide
115
6.8
Addition to C
−
C and C
−
N Double Bonds
116
6.8.1
Addition to C
−
C Double Bonds
116
6.8.2
Addition to C
−
N Double Bonds
117
6.9
β
-Fragmentation Reactions
117
6.9.1
Homolytic Fragmentation
117
6.9.2
Water Elimination, Heterolytic
-Fragmentation
and Formation of Radical Cations
β
118
6.10
Hydration and Hydrolysis of Radicals
125
6.11
Bimolecular Termination Reactions
126
References
127
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