Chemistry Reference
In-Depth Information
Cl
N
N
N
Pd
Cl
Me
Cl
Ru
d
n
4
r
4
n
g
|
0
Me
Cl
- 2 NaCl
2 NaOH
- 2 HCl
2 NaOSiMe
3
N
N
O
N
N
O
S
Pd
N
N
- 2 HOSiMe
3
Me
OH
Pd
+
Ru
O
Ru
Me
O
Me
OH
Me
S
Scheme 3.1 Preparation of [Ru(N)Me
2
(m
2
-O)
2
Pd((-)-sparteine)]
.
.
Figure 3.5 Proposed 3D body-centered, interpenetrating network structure for
[Ru
II,III
2
(H
2
TCPPT)]BF
4
: carbon (gray), hydrogen (light blue), nitrogen
(blue), oxygen (red), ruthenium (reddish brown), boron (yellow) and
fluorine (green).
corresponding aldehydes and ketones was developed using a ruthenium
catalyst in a continuous-flow reactor.
50
A cooperative NHC (N-heterocyclic
carbene) and ruthenium-based, Ru(2,2
0
-bipyrazine)
3
(PF
6
)
2
, redox catalyst
Search WWH ::
Custom Search