Chemistry Reference
In-Depth Information
FIGURE 15.1
The dependence of nanoclusters relative fraction φ
cl
on testing temperature
T
for PC. The critical temperatures of bifurcation points are indicated by arrows (explanations
are given in the text) [18].
Within the frameworks of solid body synergetics it has been shown [12],
that at structures self-organization the adaptation universal algorithm, de-
scribed by the Eq. (9.3), is realized at transition from previous point of struc-
ture instability to subsequent one. The value
m
= 1 corresponds to structure
minimum adaptivity and
m
=
m
* to maximum one. In Ref. [12] the table is
adduced, in which values A
m
,
m
and ∆
i
are given, determined by the gold
proportion rule and corresponding to spectrum of structure stability measure
invariant magnitudes for the alive and lifeness nature systems. The indicated
table usage facilitates determination of the interconnected by the power law
stability and adaptivity of structure to external influence [12].
Using as the critical magnitudes of governing parameter the values j
cl
in the indicated bifurcation points
T
0
,
T
g
' and
T
g
(
c
φ′
and
*
c
T
, accordingly)
together with the mentioned in table data [12], values
A
m
, ∆
i
and for PC can
be obtained, which are adduced i
n
Table 15.1
.
As it follows from the data of
Table 15.1, systematic reduction of parameters
A
m
and ∆
i
at the condition
m
= 1 = const is observed. Hence, within the frameworks of solid body syn-
ergetics temperature
T
g
' can be characterized as bifurcation point ordering-
degradation of nanostructure and
T
g
- as nanostructure degradation-chaos
[12].
