Chemistry Reference
In-Depth Information
The Eq. (5.16), which both qualitatively and quantitatively corresponds to
experimentally obtained dependence
A
p
(
B
) [13, 24], allows to confirm this
postulate. So, at testing temperature
T
= 293 K the value
r
p
≈ 0.8 mm for
HDPE [21]. The calculated at this condition according to the Eq. (5.16) cor-
=
B
, corresponding to the brittle-ductile transition [12], the greatest possible
value
d
fr
= 2 is reached.
d
r
-
1
FIGURE 10.8
The dependence of critical strain energy release rate
G
Ic
on parameter
a
for HDPE (1) and PS (2) [21].
In addition the obtained value
B
= 1.6 mm corresponds well to the liter-
ary data for samples with the greatest plasticity thickness [13]. Then the fast
d
fr1
reduction at B growth is observed, that corresponds completely to simi-
lar fracture toughness decrease within the frameworks of polymer fracture
two-component model [25, 26] and also corresponds to the stressed state
transition from plane-stressed to plane-strained one [13]. At
B
= 20 ÷ 25
mm the values
d
fr1
reach asymptotic magnitude, that also corresponds to the
experimental B value, obtained for transition to plane-strained state [24].
The plots of Fig. 10.8 are of interest from two points of view. Firstly, they
confirm the intercommunication of
G
Ic
and local plastic deformation zones
fractality. Secondly, such plot allows to determine the value
G
I0
in the Eq.
(10.14), which is actually material property. From the data of Fig. 10.8 it
follows, that for HDPE
G
I0
= 2.35 kJ/m
2
and for PS - 1.70 kJ/m
2
, that is very
close to the cited earlier results [22].