Chemistry Reference
In-Depth Information
crazing: a large
S
and
C
∞
values (69.8 Ǻ
2
[27] and 10 [28], accordingly), that
defines high values
d
f
and, hence, n [20].
FIGURE 9.2
The dependence of Poisson's ratio n on testing temperature
T
for PS (1), PC
(2) and PP (3). The horizontal shaded line shows the value n
*
[20].
In Fig. 9.3, the dependences n(
K
st
) for the considered epoxy polymers are
adduced where the value n
*
is indicated again by a horizontal shaded line.
As one can see, crazing is possible only for epoxy polymer samples with
K
st
= 0.50 and 1.50, having the smallest values of both n
cl
and chemical cross-
linking nodes density n
c
[29], that corresponds completely to the concepts of
Refs. [16, 30]. Exactly these epoxy polymers in compression testing show
brittle fracture (up to yield stress) that confirms experimentally the plots of
Fig. 9.3 correctness.
FIGURE 9.3
The dependence of Poisson's ratio n on the value
K
st
for EP-1 (1) and EP-2 (2).
The horizontal shaded line shows the value n
*
[20].