Chemistry Reference
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FIGURE 8.8 The optical microphotographs block, showing ZD and stable crack evolution
in blend PAASO/PC with PC content 20 mas. % sample. Enlargement 22ยข [14].
Now the equation for the fracture stress sf f estimation as a function of D cr
and sharp notch length a can be obtained. In Ref. [4], the following defini-
tion of stress intensity factor K I as a function of D cr was given:
a
a
2
-
D
(
)
KD
=
C D
,
a
=
cr
,
(8.3)
I
cr
2
cr
where C is coefficient, dependent on crack form details and external loads
concrete distribution.
One more estimation K I ( D cr ) method the Eq. (8.1) gives. Assuming
K I ( D cr ) as polymer constant [16] and equating the Eqs. (8.1) and (8.3), let
us obtain [14]:
(
)
1/ 2
D
-
3/2
s
~
a
D
.
(8.4)
cr
f
cr
The Eq. (8.4) has three characteristic features. Firstly, it shows, that at
D cr < 1.5 sf f will be decreased at a enhancement and at D cr > 1.5 will raise. If
to compare these predictions with the data of Fig. 8.9 and Refs. [1, 2], then
one can see, that they are fulfilled completely. Secondly, at D cr = 1.5 s f must
not depended on notch length, that is also c onir med experimentally [1, 2].
And thirdly, at a = 1 mm the condition sf f ~
c D should be fulfilled. As the
 
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