Luminescent Dendrimers as Ligands and Sensors of Metal Ions - Advanced Fluorescence Reporters in Chemistry and Biology - page 281

15. (a) Bergamini G, Saudan C, Ceroni P et al (2004) Proton-driven self-assembled systems based
on cyclam-cored dendrimers and [Ru(bpy)(CN) 4 ] 2 . J Am Chem Soc 126:16466-16471
(b) van de Coevering R, Kuil M, Gebbink JMK et al (2002) A polycationic dendrimer as
noncovalent support for anionic organometallic complexes. Chem Commun 15:1636-1637
16. (a) Puntoriero F, Bergamini G, Ceroni P et al (2008) Azacrown ethers with naphthyl branches.
Fluorescence properties, protonation and metal coordination. J Inorg Organomet PolymMater
18:189-194 (b) Antoni P, Malkoch M, Vamvounis G et al (2008) Europium confined cyclen
dendrimers with photophysically active triazoles. J Mater Chem 18:2545-2554
17. (a) Bergamini G, Ceroni P, Maestri M et al (2007) Cyclam cored luminescent dendrimers as
ligands for Co(II), Ni(II) and Cu(II) ions. Inorg Chim Acta 360:1043-1051 (b) Branchi B,
Ceroni P, Bergamini G et al (2006) A cyclam core dendrimer containing dansyl and
oligoethylene glycol chains in the branches: protonation and metal coordination. Chem Eur
J 12:8926-8934 (c) Gu T, Whitesell JK, Fox MA (2006) Intramolecular charge transfer in 1:1
Cu(II)/pyrenylcyclam dendrimer complexes. J Phys Chem B 110:25149-25152 (d) Bergamini
G, Ceroni P, Balzani V et al (2005) Dendrimers based on a bis-cyclam core as fluorescence
sensors for metal ions. J Mater Chem 15:2959-2964 (e) Saudan C, Ceroni P, Vicinelli V et al
(2004) Simple and dendritic cyclam derivatives. Photophysical properties, effect of proton-
ation and Zn 2+ coordination, preliminary screening as inhibitors of tumour cell growth.
Supramol Chem 16:541-548 (f) Saudan C, Ceroni P, Vicinelli V et al (2004) Cyclam-based
dendrimers as ligands for lanthanide ions. Dalton Trans 10:1597-1600 (g) Saudan C, Balzani
V, Gorka M et al (2004) Dendrimers as ligands: an investigation into the stability and kinetics
of Zn2+ complexation by dendrimers with 1,4,8,11-tetraazacyclotetradecane (Cyclam) cores.
Chem Eur J 10:899-905 (h) Saudan C, Balzani V, Gorka M et al (2003) Dendrimers
as ligands. Formation of a 2:1 luminescent complex between a dendrimer with a 1,4,8,
11-tetraazacyclotetradecane (Cyclam) core and Zn 2+ . J Am Chem Soc 125:4424-4425
18. Thomas SW, Joly GD, Swager TM (2007) Chemical sensors based on amplifying fluorescent
conjugated polymers. Chem Rev 107:1339-1386
19. (a) Sarkar K, Dhara K, Nandi M et al (2009) Selective zinc(II)-ion fluorescence sensing by a
functionalized mesoporous material covalently grafted with a fluorescent chromophore and
consequent biological applications. Adv Funct Mater 19:223-234 (b) Gouanv´ F, Schuster T,
Allard E et al (2007) Fluorescence quenching upon binding of copper ions in dye-doped and
ligand-capped polymer nanoparticles: a simple way to probe the dye accessibility in nano-
sized templates. Adv Funct Mater 17:2746-2756 (c) Yan J, Estevez MC, Smith JE et al (2007)
Dye-doped nanoparticles for bioanalysis. Nano Today 2:44-50
20. For some recent reviews, see: (a) Astruc D, Ornelas C, Ruiz J (2008) Metallocenyl dendrimers
and their applications in molecular electronics, sensing, and catalysis. Acc Chem Res
41:841-856 (b) Kaifer AE (2007) Electron transfer and molecular recognition in metallo-
cene-containing dendrimers. Eur J Inorg Chem 5015-5027
21. See for example: (a) Balzani V, Campagna S, Denti G et al (1998) Designing dendrimers
based on transition-metal complexes. light-harvesting properties and predetermined redox
patterns. Acc Chem Res 31:26-34 (b) Huisman B-H, Sch¨nherr H, Huck WTS et al (1999)
Surface-confined metallodendrimers: isolated nanosize molecules. Angew Chem Int Ed
38:2248-2251 (c) McClenaghan ND, Loiseau F, Puntoriero F et al (2001) Light-harvesting
metal dendrimers appended with additional organic chromophores: a tetranuclear heterome-
tallic first-generation dendrimer exhibiting unusual absorption features. Chem Commun
24:2634-2635
22. For some examples, see e.g.: (a) Hogan CF, Harris AR, Bond AM et al (2006) Electrochemical
studies of porphyrin-appended dendrimers. PhysChemChemPhys 8:2058-2065 (b) Jang W-D,
Nishiyama N, Zhang G-D et al (2005) Supramolecular nanocarrier of anionic dendrimer
porphyrins with cationic block copolymers modified with polyethylene glycol to enhance
intracellular photodynamic efficacy. Angew Chem Int Ed 44:419-423 (c) Loiseau F, Cam-
pagna S, Hameurlaine A et al (2005) Dendrimers made of porphyrin cores and carbazole
chromophores as peripheral units. Absorption spectra, luminescence properties, and oxidation