Chemistry Reference
In-Depth Information
Table 12.1 Continued )
O
O
1 mol%Cu source, 2 mol% ligand*
R 1 = Et, Me
+
1.4 equiv MR 1 n
*
R 1
Solvent
Entry
Ligand
Precursor
MR 1 n
Solvent
O
O
OO P
O
P
21a
O
O
Cu(OTf) 2 f)
9
ZnEt 2
CH 2 Cl 2
R 1
=
R 2
=
H
O O
21b
10
Cu(OTf) 2 f)
ZnEt 2
CH 2 Cl 2
R 1
R 2
t Bu
=
=
21g
(S) ax R 3
11
Cu(OTf) 2 f)
ZnEt 2
CH 2 Cl 2
=
SiMe 3
37b
(R) ax
(CuOTf) 2 ·C 6 H 6
(2 mol.%)
ZnEt 2
(2.4 equiv)
12
THF
Ph
O
O
O
O
O
P
NH OMe
O
P
O
O
42c
R 1 = SiMe 3 , R 2 = H
13
Cu(OAc) 2 g)
AlEt 3
Et 2 O
R 1
R 2
O
O
O
O
=
 
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