Chemistry Reference
In-Depth Information
Table 9.4
Continued
)
Me
catalyst (1-5 mol%):
Ni(COD)
2
/
ligand*
(ratio 1:1)
CN
HCN
benzene, toluene or hexane
MeO
MeO
D-
fructo
CF
3
F
Me
P
Ar
2
2
O
TrO
OTr
Ar
1
, Ar
2
=
OMe
F
O
a
b
c
d
e
f
CF
3
F
Me
O
82
Ar
1
2
P
Entry
Ligand
Ar
1
Ar
2
ee (%)
F
9
82ca
63
F
CF
3
F
10
82bc
78
CF
3
F
CF
3
F
11
82cb
42
F
CF
3
CF
3
Me
12
82bd
78
CF
3
Me
CF
3
13
82be
OMe
84
CF
3
CF
3
14
82bf
F
88
CF
3
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