Chemistry Reference
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Table 2 Theoretical parameters for the dynamic surface tension fitted at various bulk concentrations of lysozyme:
a ¼ Frumkin intermolecular interaction parameter; o 0 ¼ molar area of one segment of the protein molecule;
o 1 ¼ minimal molar area of the protein molecule; o max ¼ maximal molar area of the protein molecule;
b ¼ adsorption equilibrium constant; D ¼ diffusion coefficient
o 0 ,m 2 mol 1
( 10 5 )
o 1 ,m 2 mol 1
( 10 6 )
o max, m 2 mol 1
( 10 7 )
b, m 3 mol 1
( 10 3 )
D, m 2 s 1
( 10 10 )
Concentration,
mol L 1
a
1 10 8
0.2
9.95
6.72
5.08
2
3
1 10 8
0.2
9.95
6.72
5.08
2
1
1 10 8
0.8
6.05
6.72
2.94
3
1
1 10 8
0.69
4.95
6.72
2.54
3
1
1 10 8
0.69
4.95
6.72
2.54
3
1
1 10 8
0.7
3.08
6.72
1.02
2
1
1 10 8
0.69
4.95
6.72
2.54
2
0.03
1 10 8
0.69
4.95
6.72
2.54
1
0.10
1 10 8
0.69
4.95
6.72
2.54
1
0.02
 
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