Biomedical Engineering Reference
In-Depth Information
The second property expected for non-equilibrium processes is the lack of dependence
(Fig. 2.6, curve 1) or weak dependence (curve 2) of the experimental rate constant of ET in
both Marcus regions (inverted and non-inverted), compared to that predicted by the classic
Marcus expression (curve 3).
Another approach to solvent fluctuation control of reactions in solution based on the
Kramer model (Kramer, 1940; Sumi, 1999 and references therein). According to this
model a transition over a double-well potential occurs as a result of zigzag diffusion.
An important parameter of the theory is the relaxation time of the average motion of the
medium
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