Density Functional Theory Calculations on Cobalt and Platinum Transition Metal Clusters - Metallic Systems: A Quantum Chemist's Perspective - page 362

Non-SO

SO

2.604

2.612

2.606 2.613

2.612

2.606
2,611

2.613

2.604

2.607

2.607

2.612

2.607

2.612

2.607

2.611

2.625

2.536

2.625

2.625

2.624

2.531

2.557

2.959

2.946

2.566

2.625

2.625

2.624

2.536

2.626

2.531

2.523

2.524 2.531

2.530

2.616

2.616

2.627

2.626

2.540

2.540

2.542

2.543

2.589

2.595

2.662

2.602

2.662

2.661

2,590

2.661

2.590

2.662

2.590

2.590

2.590

2.590

2.662

2.661

2.663

2.662

2.663

2.661

2.546 2.521

2.586 2.570

2.457 2.453 2.458 2.476

2.583

2.569

2.547

2.519

2.469

2.462

2.538 2.585 2.580

2.550

2.541

2.553 2.582 2.583

2.467 2.463

FIGURE 10.7 Relaxed. geometries. of. Pt 5 . isomers. for. the. most. stable. spin. multiplicity.
of. each. isomer. with. and. without. SO. coupling. effects. (distances. are. in. Å).. (PCCP. Owner.
Societies,.Sebetci,.A.,.Does.spin.orbit.coupling.effect.favour.planar.structures.for.small.plati-
num. clusters,. Phys. Chem. Chem. Phys .,. 11,. 921,. 2009.. Reproduced. by. permission. of. The.
Royal.Chemical.Society.).