Biomedical Engineering Reference
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and ends with low isolation yields. Separating halide and acetylene groups
into two different molecules allows easier synthetic access and offers a greater
variety of monomer choices but meanwhile invites the risk of cross-linking
reactions. Control of the polycoupling conditions is thus a necessity if one in-
tends to synthesize soluble hyperbranched polymers with desired structures
and properties.
Scheme 4
Formation of cross-linked particles in the polymerization of A 2 +B 2 +B 3
monomers
Scheme 5 A 2 +B 3 approach toward soluble, functional hb -PAEs
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