Biomedical Engineering Reference
In-Depth Information
tion of the elastomer is a non-silicone one—such as EPDM —can be obtained
via a hybrid-containing silicone crosslinking agent [155-157].
5
Conclusion
Despite the incompatibility of silicone towards many polymers, several tech-
niques have been more or less successfully developed to produce silicone
containing physical blends. Although compatibilization remains essentially of
academic interest only, many industrial applications for IPNs are a testimony
to their growing importance. Silicone blends allow researchers to introduce
specific properties such as impact resistance or low surface energy to poly-
mers that fundamentally lack these characteristics. On the other hand, it must
be acknowledged that silicone blends and related fields of research are still
open to further development and will undoubtedly lead to a wide range of
future industrial applications.
Acknowledgements We gratefully acknowledge Dr. Edeline Wentrup-Byrne (Queensland
University of Technologie, Brisbane, Australia) for her kind help.
References
1. Goldberg EP (1961) Resinous mixtures of polysiloxanes and polymers from carbon-
ates of dihydric phenols. US Patent 2 999 835
2. Bostick EE, Jaquiss DBG (1973) Compatible polycarbonate-siloxane composition.
US Patent 3 751 519, General Electric, US, p 2
3. Meyer RV, Dhein R, Fahnler F (1979) Polyamide blends with high impact strength,
DE Patent 2 734 693
4. Hill DJT et al. (1996) Development of wear-resistant thermoplastic polyurethane
by blending with poly(dimethyl siloxane). I. Physical properties. J Appl Poly Sci
61(10):1757-1766
5. Bremner T et al. (1997) Development of wear-resistant thermoplastic polyurethanes
by blending with poly(dimethyl siloxane). II. A packing model. J Appl Poly Sci
65(5):939-950
6. Damrongsakkul S, Sinweeruthai R, Higgins JS (2003) Processability and chemical re-
sistance of the polymer blend of thermoplastic polyurethane and polydimethylsilox-
ane. Macromolecular Symposia. 7th Eur Symp Polymer Blends, Lyon-Villeurbanne,
27-29 May 2002, pp 411-419
7. Wu S (1987) Formation of dispersed phase in incompatible polymer blends: interfa-
cial and rheological effects. Poly Eng Sci 27(5):335-343
8. Maric M, Macosko CW (2002) Block copolymer compatibilizers for polystyr-
ene/poly(dimethylsiloxane) blends. J Polym Sci Part B: Polym Phys 40(4):346-357
9. Chuai CZ et al. (2004) The effect of compatibilization and rheological proper-
ties of polystyrene and poly(dimethylsiloxane) on phase structure of polystyr-
ene/poly(dimethylsiloxane) blends. J Polym Sci Part B: Polym Phys 42(5):898-913
Search WWH ::




Custom Search