HIGH-VALENT Cr, Mn, AND Fe SPECIES - Oxidation of Amino Acids, Peptides, and Proteins: Kinetics and Mechanism - page 378

324 Loegager, T., Holcman, J., Sehested, K., and Pedersen, T. Oxidation of ferrous ions
by ozone in acidic solutions. Inorg. Chem. 1992, 31 , 3523-3529.
325 Pestovsky, O. and Bakac, A. Identification and characterization of aqueous
ferryl(IV) ion. Preprints of Extended Abstracts presented at the ACS National
Meeting, American Chemical Society, Division of Environmental Chemistry 2006,
46 (2), 573-577.
326 Jacobsen, F., Holcman, J., and Sehested, K. Activation parameters of ferryl ion
reactions in aqueous acid solution. Int. J. Chem. Kinetics 1997, 29 , 17-24.
327 Martire, D.O., Careganato, P., Furlong, J., Allegretti, P., and Gonzalez, M.C. Kinetic
study of the reactions of oxoiron(IV) with aromatic substrates in aqueous solu-
tions. Int. J. Chem. Kinet. 2002, 34 , 488-494.
328 Fiedler, A.T. and Que, L., Jr. Reactivities of Fe(IV) complexes with oxo, hydroxo,
and alkylperoxo ligands: an experimental and computational study. Inorg. Chem.
2009, 48 , 11038-11047.
329 Wang, W., Zhang, M., Buhlmann, P., and Que, J.L. Redox potential and C-H bond
cleaving properties of a nonheme Fe IV =O complex in aqueous solution. J. Am.
Chem. Soc. 2010, 132 , 7638-7644.
330 Comba, P., Fukuzumi, S., Kotani, H., and Wunderlich, S. Electron-transfer proper-
ties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine
ligand. Angew. Chem. Int. Ed. 2010, 49 , 2622-2625.
331 Hong, S., Lee, Y., Cho, K., Sundaravel, K., Cho, J., Kim, M.J., Shin, W., and Nam,
W. Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-
oxo complex in oxygenation reactions. J. Am. Chem. Soc. 2011, 133 , 11876-
11879.
332 Park, J., Morimoto, Y., Lee, Y., Nam, W., and Fukuzumi, S. Proton-promoted
oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-
oxo complex. J. Am. Chem. Soc. 2012, 134 , 3903-3911.
333 Klinker, E.J., Shaik, S., Hirao, H., and Que, L., Jr. A two-state reactivity model
explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme
oxoiron(IV) complexes. Angew. Chem. Int. Ed. 2009, 48 , 1291-1295.
334 Abouelatta, A.I., Campanali, A.A., Ekkati, A.R., Shamoun, M., Kalapugama, S.,
and Kodanko, J.J. Oxidation of the natural amino acids by a ferryl complex:
kinetic and mechanistic studies with peptide model compounds. Inorg. Chem.
2009, 48 , 7729-7739.
335 Ekkati, A.R. and Kodanko, J.J. Targeting peptides with an iron-based oxidant:
cleavage of the amino acid backbone and oxidation of side chains. J. Am. Chem.
Soc. 2007, 129 , 12390-12391.
336 Kotani, H., Suenobu, T., Lee, Y., Nam, W., and Fukuzumi, S. Photocatalytic genera-
tion of a non-heme oxoiron(IV) complex with water as an oxygen source. J. Am.
Chem. Soc. 2011, 133 , 3249-3251.
337 Hirao, H., Li, F., Que, L., and Morokuma, K. Theoretical study of the mechanism
of oxoiron(IV) formation from H 2 O 2 and a nonheme iron(II) complex: O-O
cleavage involving proton-coupled electron transfer. Inorg. Chem. 2011, 50 ,
6637-6648.
338 Bryant, J.R. and Mayer, J.M. Oxidation of C-H bonds by [(bpy)2(py)R uI VO] 2 +
occurs by hydrogen atom abstraction. J. Am. Chem. Soc. 2003, 125 , 10351-
10361.