Chemistry Reference
In-Depth Information
FIGURE 9.15.
Energy of the four quartet sublevels of
o-6b
as a function of the external
field H parallel to
z
,
x
, and
y
, respectively, calculated for
jD
/hc
j¼
0.357 cm
1
,
jE/
hc
j¼
0.0136 cm
1
(
g¼
2.003). The
z
1 transition at low field is reproduced as a very weak band only
in the simulated spectrum. However, the calculated
x
- and
y
-transitions can be identified in the
simulated as well as in the experimental spectrum.
simulated spectrum at 1135, 2130, and 4125 G can be assigned to transitions with the
external magnetic field oriented parallel to the
z
-axis. These signals cannot be seen in
the experimental spectrum, though. However, the calculated
x-
and
y
-transitions can
be identified in the simulated as well as in the experimental spectrum.
