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15
15
14
14
130
O 2 H 2 O
O 2 H 2 O
13
13
NO 3 N 2
10
12
120
12
11
11
20
NO 3 N 2 O
MnO 2 Mn 2 +
110
10
10
9
9
30
100
8
8
NO 2 NO 3
NO 3 NO 2
7
40
7
90
NO 3 NH 4 +
6
6
NH 4 + NO 2
50
80
5
5
4
4
60
70
3
3
2
2
70
60
1
1
80
50
0
0
Fe(OH) 3 Fe 2 +
1
1
Fe 2 + Fe(OH) 3
90
40
CH 2 O CH 3 OH
SO 4 2 HS
100
30
H 2 S SO 4 2
110
20
CO 2 CH 4
120
10
H 2 H +
H + H 2
130
CH 2 O CO 2
1
10
Figure 4.3 Free energy changes in redox reactions mediated by microbes. (a) Oxidation of reduced inorganic compounds linked to reduction
of O 2 . (b) Oxidation of organic matter 'CH 2 O' linked to reduction of various organic and inorganic oxidants. pH = 7 and unit oxidant and
reductant activities except ( Mn 2 + ) =
0 . 2mM and ( Fe 2 + ) =
1mM
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