Biomedical Engineering Reference
In-Depth Information
(A) Coefficient | Case
Exp.
mole/gram
1
2
3
4
Cd
25.53
29.58
62.68
187.30
-6.53
Ni
22.57
43.73
67.24
201.40
-1.94
Zn
25.40
53.4
65.29
211.10
0.36
CdNi
30.59
32.75
116.00
42.71
0.02
CdZn
31.03
47.59
112.80
57.55
1.28
NiCd
30.39
45.32
128.80
55.28
12.62
NiZn
29.94
47.78
113.60
57.74
-3.17
ZnCd
31.69
38.20
112.00
48.16
1.00
ZnNi
32.07
56.72
120.30
66.68
14.49
CdNiZn
31.27
31.87
167.60
-78.40
0.30
CdZnNi
28.80
32.57
162.60
-77.70
-0.96
NiCdZn
30.93
44.71
193.60
-65.50
13.17
NiZnCd
28.80
24.26
156.20
-86.00
-4.68
ZnCdNi
38.10
31.82
169.70
-78.40
2.56
ZnNiCd
28.69
30.96
167.30
-79.30
6.26
Simultaneous
41.72
36.41
191.70
410.20
-30.40
(B) Coefficient | Case
Exp. mole/gram
1 2 3 4
Cd 50.35 45.60 756.48 334.45 -16.11
Ni 49.42 38.00 268.98 326.85 -11.68
Zn 52.27 46.14 -202.78 334.99 -7.64
CdNi 70.31 50.81 557.30 90.26 -8.63
CdZn 69.39 55.57 82.16 95.02 -3.49
NiCd 61.10 46.83 553.32 86.28 -8.19
NiZn 67.60 50.40 76.99 89.85 6.78
ZnCd 59.34 54.47 560.96 93.92 3.00
ZnNi 69.16 52.05 78.64 91.50 8.20
CdNiZn 74.07 39.35 -102.89 -128.61 -4.86
CdZnNi 73.12 40.19 -102.05 -127.77 0.24
NiCdZn 67.28 37.77 -104.47 -130.19 -2.02
NiZnCd 66.05 37.36 -104.88 -130.60 1.84
ZnCdNi 64.08 40.10 -102.14 -127.86 4.35
ZnNiCd 68.13 39.51 -102.73 -128.45 3.77
Simultaneous 72.87 40.68 -1505.70 673.19 -50.24
Table 7. Modified (A) and Native (B) columns experimental and calculated total metals
bound, Case 1: All unique single metal bonds are included when appropriate in the
sequential case and only all three unique sites along with the common site for the
simultaneous case. Case 2: Same as case 1 except for the simultaneous all three, three metal
binding site types are active along with the unique sites and common site. Case 3: The
unique metal coefficients are not included in the simultaneous portion of the matrix
calculation. Case 4: The unique metal coefficients are only included when they are the first
metal on the column
