Chemistry Reference
In-Depth Information
The
tetravalent
nature of the bonding of carbon. This means that carbon
needs four bonds to complete an
octet
of electrons, in other words to fill
its
valence
outer shell.
n
The ability to form strong
single covalent
bonds where the bonded atoms
share an electron pair. Carbon atoms can bond in this way to an almost
unlimited number of other carbon atoms. For
acyclic
compounds there
are no rings. This gives either
straight chains
which have no branch
points, or
branched chains
which do have branch points. In
cyclic
com-
pounds there can be different sized rings.
n
The ability to form double or triple
multiple bonds
, where more than
one electron pair is shared with another carbon atom.
n
The ability to bond covalently with many
heteroatoms
, other non-carbon
atomic species such as
H
,
O
,
N
,
S
,
P
, and halogens. These bonds are either
single or multiple.
n
1.3 MOLECULES, FORMULAE, AND STRUCTURES
Carbon can be part of different bonding arrangements in the group of bonded
atoms that form a
molecule
. Because a molecular
formula
only gives the type
and number of atoms in a molecule, it does not tell anything about the
structure
of the molecule. The structure gives information of how the atoms are joined
together. For example, 366,319 structures with a molecular formula of C
20
H
42
are possible. To simplify this problem, it is necessary to classify and subclassify
organic substances.
The best place to start is with
hydrocarbons
, which are compounds that con-
tain only carbon and hydrogen.
Figure 1.1
shows how related structures and
properties are used to classify hydrocarbons. As a first stage, hydrocarbons can
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