Chemistry Reference
In-Depth Information
Table 12.13 Examples of enantiomer production and separation using membrane
bioreactors.
Enantioselective
biocatalyst
Membrane
reactor
Isolated enantiomer
Reaction
References
Dehydrogenase
MBR
(L)-phenylalanine
Dehydrogenation
[60]
Lipase from
C.
Cylindracea
BMR
(S)-ibuprofen acid
Hydrolysis
[61]
Lipase from
Serratia
marcescens
(
รพ
)-(2S, 3R)-3-(4-
methoxyphenyl)
glycidic acid
[62]
Acinobacter sp.
AK 226
MBR
(S)-ibuprofen acid
Denitrification
[63]
Lipase from
Rhizomucor
miehei
Byphasic-BMR
(S)-bultil ibuprofen
ester
Esterification
[64]
a
-chymotrypsin
(L)-phenylalanine
Hydrolysis
[65]
Lipase from
Pseudomonas
sp.
BMR
(1R;2R)-2-methyl-1-
cyclohexanol
Transesterification [66]
Lipase from
Candida rugosa
Byphasic-BMR
(S)-naproxen acid
Hydrolysis
[58,59,67]
Lipase from
Candida rugosa
Emulsion-BMR
[68]
Baker's yeast
Byphasic-MBR
R-citronellol
Reduction
[69]
MBR, membrane bioreactor; BMR, biocatalytic membrane reactor.
Table 12.14 Some examples of enantioselective membranes.
Membrane material
Chirality
Compound
separated
References
Poly[(acrylonitrile)-co-
(acrylic acid)]
Imprinted polymer with
amino acids
Amino acids
[71]
Chiral helical poly[
p
-
(oligopinanylsiloxanyl)
phenylacetylene]s
Chiral polymer
Phenylacetylenes
containing pinanyl
groups
[72]
Polyamide
Chiral polymer
[73]
Polyamide
Chiral polymer synthesized
with Schiff's base
complexes of Cu (II) and
Zn (II)
[74]
Nitrocellulose
Chiral polymer
[75]
Composite membrane
(polysulphone
polymerized with l-lysine
and piperazine
monomers with trimesoyl
chloride)
Chiral polymer
Phenylacetylenes
containing pinanyl
groups
[76]
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