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[2] (a) Khand, I.U., Knox, G.R, Pauson, P.L., and Watts, W.E. (1971) A cobalt induced
cleavage reaction and a new series of arenecobalt carbonyl complexes. J. Chem. Soc.
Chem. Commun. , 36a-36a; (b) Khand, I.U., Knox, G.R, Pauson, P.L., Watts, W.E and
Foreman, M.I. (1973) Organocobalt complexes. Part II. Reaction of acetylenehexacar-
bonyldicobalt complexes, (R 1 C 2 R 2 )Co 2 (CO) 6 , with norbornene and its derivatives.
J. Chem. Soc., Perkin Trans. 1 , 977-981.
[3] Reviews of the Pauson-Khand reaction: (a) Pauson. P.L. (1985) The Khand reaction: A
convenient and general route to a wide range of cyclopentenone derivatives. Tetrahe-
dron , 41 , 5855-5860; (b) Pauson. P.L. (1987) Organometallics in Organic Synthesis ,
Springer, Berlin; (c) Schore, N.E. (1991) The Pauson-Khand cycloaddition reaction
for synthesis of cyclopentenones. Org. React. , 40 , 1-90; (d) Perez-Castells, J. (2006)
Cascade reactions involving Pauson-Khand and related processes. Top. Organomet.
Chem. , 19 , 207-257; (e) Brummond, K.M. and Kent, J.L. (2000) Recent advances
in the Pauson-Khand reaction and related [2
1] cycloadditions. Tetrahedron , 56 ,
3263-3283; (f) Urgoiti, J.B., Anorbe, L., Perez-Serrano, L., Domınguez, G. and Perez-
Castells, J. (2004) The Pauson-Khand reaction, a powerful synthetic tool for the
synthesis of complex molecules. Chem. Soc. Rev. , 33, 32-42.
[4] Enocki, N., Furusaki, A., Suehiro, K., Ishida, R., and Matsumoto, T. (1983) Epoxy-
dictymene, a new diterpene from the brown alga. Tetrahedron Lett. , 24 , 4341-4342.
[5] (a) Jamison, T. F., Shambayati, S., Crowe, W. E. and Schreiber, S. L. (1994) Cobalt-
mediated total synthesis of (
+
2
+
+
)-epoxydictymene. J. Am. Chem. Soc. , 116 , 5505-
5506.
[6] Shambayati, S., Crowe, W. E. and Schreiber, S. L. (1990) N-oxide promoted Pauson-
Khand cyclizations at room temperature. Tetrahedron Lett. , 31 , 5289-5292.
[7] Billington, D. C., Helps, I. M., Pauson, P. L., Thomson, W. and Willison, D. J.
(1988) The effect of ultrasound and of phosphine and phosphine-oxides on the Khand
reaction. J. Organomet. Chem. , 354 , 233-242.
[8] (a) Piers, E. and Karunaratne, V. (1984) Methylenecyclopentane annulation: a synthe-
sis of the sesquiterpenoid (
)-pentalenene. J. Chem. Soc. Chem. Commun. , 959-960;
(b) Piers, E. and Karunaratne, V. (1989) Bifunctional reagents in organic synthesis.
Total syntheses of the sesquiterpenoids (
±
±
)-pentalenene and (
±
)-9-epi-pentalenene.
Can. J. Chem. , 67 , 160-164.
[9] (a) Paquette, L. A. and Annis, G. D. (1982). Total synthesis of (
±
)-pentalenene. J. Am.
Chem. Soc. , 104 , 4504-4506; (b) Mehta, G. and Rao, K. S. (1986) General transan-
nulation approach to angular triquinanes. Total syntheses of (
±
)-pentalenene and
(
)-epi-pentalenene. J. Am. Chem. Soc. , 108 , 8015-8021; (c) Ohfune, Y., Shirama, H.
and Matsumoto, T. (1976) Formolysis of protoilludyl cation equivalents a new mode
of rearrangement of bicyclo[4.2.0]oct-2-yl cation. Tetrahedron Lett. 2869-2872; (d)
Crimmins, M. T. and DeLoach, J. A. (1986) Intramolecular photocycloadditions-
cyclobutane fragmentation: total synthesis of (
±
±
)-pentalenene, (
±
)-pentalenic acid,
and (
)-deoxypentalenic acid. J. Am. Chem. Soc. , 108 , 800-806; (e) Hua, D. H.
(1986) Asymmetric total synthesis of (
±
)-pentalenene via chiral sulfinylallyl an-
ions. Hydrolytic ring closure of enol thioether ketones. J. Am.Chem. Soc. , 108 ,
3835-3835; (f) Pattenden, G. and Teague, S. J. (1987) Transannular cyclisation
as a stratagem in synthesis. A total synthesis of (
+
±
)-pentalenene. Tetrahedron , 43 ,
5637-5652.
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