Chemistry Reference
In-Depth Information
(R
1
C
2
R
2
)Co
2
(CO)
6
, with norbornene and its derivatives,
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intramolecular cyclization of
-enynes,
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[4] For an early example, see: B. E. La Belle, M. J. Knudsen, M. M. Olmstead, H. Hope,
M. D. Yanuck, and N. E. Schore, Synthesis of 11-oxatricyclo[5.3.1.0
2,6
]undecane
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[5] P. Magnus, C. Exon, and P. Albaugh-Robertson, Dicobaltoctacarbonyl-alkyne com-
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of coriolin and hirsutic acid,
Tetrahedron
41
, 5861 (1985).
[6] C. Ferrer, J. Benet-Buchholz, A. Riera, and X. Verdaguer, Phosphine-alkene ligands
as mechanistic probes in the Pauson-Khand reaction,
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and references cited therein.
[7] See the Chapter by M. A. Pericas
et al
. in this topic.
[8] H. Greenfield, H. W. Sternberg, R. A. Friedel, J. H. Wotiz, R. Marby, and I. Wender,
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[9] (a) V. Rautenstrauch, P. Megard, J. Conesa, and W. Kuster, 2-Pentylcyclopent-2-en-1-
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[10] P. L. Pauson, The Khand reaction. A convenient and general route to a wide range of
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Tetrahedron
41
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[11] See: M. Christmann and S. Brase (Eds.),
Asymmetric Synthesis - The Essentials, 2
nd
ed.
, Wiley-VCH, Weinheim (2008); Part I: Chiral auxiliaries in asymmetric synthesis.
[12] Seminal references: (a) P. Bladon, P. L. Pauson, H. Brunner, andR. Eder, Optisch aktive
ubergangsmetall-komplexe. XCV. Optisch reines 3a,4,5,6,7,7a-hexahydro-2-phenyl-
4,7-methano-1H-inden-1-on durch asymmetrische Khand-reaktion,
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Chem.
355
, 449 (1988); (b) A. M. Hay, W. J. Kerr, G. G. Kirk, and D. Middle-
miss, Highly efficient enantioselective Pauson-Khand reactions,
Organometallics
14
,
4986 (1995); (c) J. Castro, A. Moyano, M. A. Pericas, A. Riera, A. Alvarez-Larena,
and J. F. Piniella, The first alkyne-dicobaltcarbonyl complex with a bidentate chi-
ral ligand with Co-P and Co-N coordination,
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585
, 53 (1999);
(d) J. Castro, A. Moyano, M. A. Pericas, A. Riera, A. Alvarez-Larena, and J. F.
Piniella, Acetylene-dicobaltcarbonyl complexes with chiral phosphinooxazoline lig-
ands: structural characterization, and application to enantioselective intermolecular
Pauson-Khand reactions,
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122
, 7944 (2000); (e) K. Hiroi, T. Watan-
abe, R. Kawagishi, and I. Abe, Catalytic use of chiral phosphine ligands in asymmetric
Pauson-Khand reactions,
Tetrahedron: Asymmetry
11
, 797 (2000); (f) X. Verdaguer,
A. Moyano, M. A. Pericas, A. Riera, M. A. Maestro, and J. Mahıa, A new chiral
bidentate (P,S) ligand for the asymmetric intermolecular Pauson-Khand reaction,
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Am. Chem. Soc.
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,