Chemistry Reference
In-Depth Information
Extracting solvent 5ml of a 1:3 mixture of toluene and 4-methylpentan-2-one Phosphorus 0-
0.8µg
*Organic phase volume was assumed to be 5ml
†7ml of extracting solvent were used
Source: Reproduced with permission from Elsevier Science [172]
Table 3.12 Effect of other ions
Concentration mol L −1
Ion
Added as
Absorbance*
None
0.549
Na + , Cl−
NaCl
0.3
0.545
K +
KCl
1×10 −2
0.548
SO 4 2−
Na 2 SO 4
1×10 −2
0.552
Ca 2+
CaCl 2
1×10 −2
0.551
Mg 2+
MgCl 2
1×10 −2
0.548
HCO 3 -
NaHCO 1
1×10 −2
0.556
Al 3+
K Al(SO 4 ) 2
1×10 −3
0.550
Fe 3+
FeNH 4 (SO 4 ) 2
1×10 −3
0.551
NH 4 Cl
1×10 −3
NH4+
0.557
NO 3 -
NaNO 3
1×10 −3
0.548
Cr 3+
CrCl 3
1×10 −3
0.549
Mn 2+
MnCl 2
1×10 −3
0.549
Co 2+
CoCl 2
1×10 −3
0.549
Cd 2 +
CdCl 2
1×10 −3
0.552
Ni 2+
NiCl 2
1×10 −3
0.549
Cu 2+
CuCl 2
1×10 −3
0.553
Zn 2 +
ZnCl 2
1×10 −3
0.546
Br−
NaBr
1×10 −3
0.546
Na 2 B 4 O 7
B(III)
1×10 −3
0.552
SiO 3 2 -
Na 2 SiO 3
5×10− 4
0.553
VO 3 -
NH 4 VO 3
1×10−5
0.556
WO 4 2-
(NH 4 ) 10 W 12 O 41
1×10 −5
0.554
I -
Nal
1×10 −5
0.550
5×10 −6
Laurylsulphate
Na salt
0.549
 
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