Chemistry Reference
In-Depth Information
Extracting solvent 5ml of a 1:3 mixture of toluene and 4-methylpentan-2-one Phosphorus 0-
0.8µg
*Organic phase volume was assumed to be 5ml
†7ml of extracting solvent were used
Source: Reproduced with permission from Elsevier Science [172]
Table 3.12
Effect of other ions
Concentration mol L
−1
Ion
Added as
Absorbance*
None
0.549
Na
+
, Cl−
NaCl
0.3
0.545
K
+
KCl
1×10
−2
0.548
SO
4
2−
Na
2
SO
4
1×10
−2
0.552
Ca
2+
CaCl
2
1×10
−2
0.551
Mg
2+
MgCl
2
1×10
−2
0.548
HCO
3
-
NaHCO
1
1×10
−2
0.556
Al
3+
K Al(SO
4
)
2
1×10
−3
0.550
Fe
3+
FeNH
4
(SO
4
)
2
1×10
−3
0.551
NH
4
Cl
1×10
−3
NH4+
0.557
NO
3
-
NaNO
3
1×10
−3
0.548
Cr
3+
CrCl
3
1×10
−3
0.549
Mn
2+
MnCl
2
1×10
−3
0.549
Co
2+
CoCl
2
1×10
−3
0.549
Cd
2
+
CdCl
2
1×10
−3
0.552
Ni
2+
NiCl
2
1×10
−3
0.549
Cu
2+
CuCl
2
1×10
−3
0.553
Zn
2
+
ZnCl
2
1×10
−3
0.546
Br−
NaBr
1×10
−3
0.546
Na
2
B
4
O
7
B(III)
1×10
−3
0.552
SiO
3
2
-
Na
2
SiO
3
5×10−
4
†
0.553
VO
3
-
NH
4
VO
3
1×10−5
0.556
WO
4
2-
(NH
4
)
10
W
12
O
41
1×10
−5
0.554
I
-
Nal
1×10
−5
0.550
5×10
−6
†
Laurylsulphate
Na salt
0.549
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