Environmental Engineering Reference
In-Depth Information
interaction matrix, the result is
J
xx
(
q
)=
1
(
q
)sin
2
θ
0
cos
2
θ
0
+
2
{J
(
q
+
Q
)+
J
(
q
−
Q
)
}
J
J
yy
(
q
)=
1
(6
.
1
.
14)
2
{J
(
q
+
Q
)+
J
(
q
−
Q
)
}
J
xy
(
q
)=
−J
yx
(
q
)=
i
2
{J
(
q
+
Q
)
−J
(
q
−
Q
)
}
cos
θ
0
,
where
J
xy
(
q
) is now non-zero. Neglecting the longitudinal response, as
we may in a weakly anisotropic system, we may calculate the response
functions by introducing these coupling parameters in (6.1.8). In order
to estimate the (
xy
)-components of the MF susceptibility, or
A
B
+
h
ex
in eqn (6.1.9), we may utilize their relation to the derivatives of the
free energy, as expressed in eqn (2.2.18). The free energy for the
i
th
ion, including the Zeeman contribution from the exchange field of the
surrounding ions, is
±
F
(
i
)=
f
0
+
f
(
u
=cos
θ
)
−
h
J
z
cos
θ
−
h
⊥
J
z
sin
θ
cos (
φ
−
φ
0
)
,
(6
.
1
.
15
a
)
with
φ
0
=
Q
·
R
i
+
ϕ
,and
h
=
J
z
J
(
0
)cos
θ
0
;
h
⊥
=
J
z
J
(
Q
)sin
θ
0
.
(6
.
1
.
15
b
)
H
J
is again, as in (6.1.4), the usual crystal-field Hamiltonian, except that
B
6
is neglected. The function
f
(
u
) is given by (2.2.17) in terms of
κ
l
(
T
),
with
κ
6
= 0. From (6.1.15), the equilibrium angles are determined by
f
(
u
0
)sin
θ
0
+
h
−
J
z
sin
θ
0
−
h
⊥
J
z
cos
θ
0
=0
,
and
φ
=
φ
0
.
f
(
u
) is the derivative of
f
(
u
) with respect to
u
,and
u
0
=cos
θ
0
. With sin
θ
0
= 0, this equation leads to
f
(
u
0
)cos
θ
0
=
2
cos
2
θ
0
.
J
z
{J
(
0
)
−J
(
Q
)
}
(6
.
1
.
16)
The spin-wave parameters may then be derived as
J
z
(
A
+
B
+
h
ex
)=
F
θθ
(
i
)
=
f
(
u
0
)sin
2
θ
0
−
f
(
u
0
)cos
θ
0
+
h
J
z
cos
θ
0
+
h
⊥
J
z
sin
θ
0
B
+
h
ex
)=
F
φφ
(
i
)
/
sin
2
θ
0
=
h
⊥
J
z
(
A
−
J
z
/
sin
θ
0
.
Introducing the values of the exchange fields and applying the equilib-
rium condition (6.1.16), we then find that
f
(
u
0
)
/
sin
2
θ
0
+
A
+
B
+
h
ex
=
{
J
z
}
J
z
J
(
Q
)
(6
.
1
.
17)
A
−
B
+
h
ex
=
J
z
J
(
Q
)
.
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