Environmental Engineering Reference
In-Depth Information
interaction matrix, the result is
J xx ( q )= 1
( q )sin 2 θ 0
cos 2 θ 0 +
2 {J
( q + Q )+
J
( q Q )
}
J
J yy ( q )= 1
(6 . 1 . 14)
2 {J
( q + Q )+
J
( q Q )
}
J xy ( q )= −J yx ( q )= i
2 {J ( q + Q ) −J ( q Q ) } cos θ 0 ,
where
J xy ( q ) is now non-zero. Neglecting the longitudinal response, as
we may in a weakly anisotropic system, we may calculate the response
functions by introducing these coupling parameters in (6.1.8). In order
to estimate the ( xy )-components of the MF susceptibility, or A
B + h ex
in eqn (6.1.9), we may utilize their relation to the derivatives of the
free energy, as expressed in eqn (2.2.18). The free energy for the i th
ion, including the Zeeman contribution from the exchange field of the
surrounding ions, is
±
F ( i )= f 0 + f ( u =cos θ )
h
J z
cos θ
h
J z
sin θ cos ( φ
φ 0 ) ,
(6 . 1 . 15 a )
with φ 0 = Q · R i + ϕ ,and
h =
J z J
( 0 )cos θ 0
;
h =
J z J
( Q )sin θ 0 .
(6 . 1 . 15 b )
H J is again, as in (6.1.4), the usual crystal-field Hamiltonian, except that
B 6 is neglected. The function f ( u ) is given by (2.2.17) in terms of κ l ( T ),
with κ 6 = 0. From (6.1.15), the equilibrium angles are determined by
f ( u 0 )sin θ 0 + h
J z
sin θ 0
h
J z
cos θ 0 =0 ,
and φ = φ 0 . f ( u ) is the derivative of f ( u ) with respect to u ,and
u 0 =cos θ 0 . With sin θ 0
= 0, this equation leads to
f ( u 0 )cos θ 0 =
2
cos 2 θ 0 .
J z
{J
( 0 )
−J
( Q )
}
(6 . 1 . 16)
The spin-wave parameters may then be derived as
J z
( A + B + h ex )= F θθ ( i )
= f ( u 0 )sin 2 θ 0
f ( u 0 )cos θ 0 + h
J z
cos θ 0 + h
J z
sin θ 0
B + h ex )= F φφ ( i ) / sin 2 θ 0 = h
J z
( A
J z
/ sin θ 0 .
Introducing the values of the exchange fields and applying the equilib-
rium condition (6.1.16), we then find that
f ( u 0 ) /
sin 2 θ 0 +
A + B + h ex =
{
J z }
J z J
( Q )
(6 . 1 . 17)
A
B + h ex =
J z J
( Q ) .
Search WWH ::




Custom Search