Environmental Engineering Reference
In-Depth Information
is the usual Bose population-factor, we find to first order in 1
/J
:
N
q
=
J
a
q
a
q
=
J
(1
1
J
z
−
−
m
)
,
(5
.
2
.
24)
with
N
q
N
q
1
1
J
1
a
q
a
q
m
=
m
q
=
and
1
J
(
u
q
α
q
−
v
q
α
+
m
q
=
v
q
α
−
q
)(
u
q
α
q
−
−
q
)
J
u
q
n
q
+
v
q
(
n
q
+1)
1
=
(5
.
2
.
25)
J
A
q
,
n
q
+
2
−
2
1
=
E
q
which is positive and non-zero, even when
n
q
=0at
T
=0.
The second-order contribution to the Hamiltonian is
H
2
=
i
B
1
8
J
(
a
i
a
i
+
a
i
a
i
)+
C
1
a
i
a
i
a
i
a
i
+
a
i
a
i
a
i
a
i
)
+
C
2
(
a
i
a
i
a
i
a
i
+
a
i
a
i
a
i
a
i
)+
C
3
(
a
i
a
i
a
i
a
i
ij
J
(
ij
)
2
a
i
a
j
a
i
a
j
−
a
i
a
i
a
i
a
j
,
−
4
a
i
a
j
a
j
a
j
−
(5
.
2
.
26)
with
J
2
2
105
B
6
J
(6)
cos 6
φ
1
B
2
J
(2)
C
1
=
−
−
J
2
4
B
6
J
(6)
cos 6
φ
1
B
2
J
(2)
+
19
4
(5
.
2
.
27)
C
2
=
−
1
J
2
1
4
B
6
J
(6)
cos 6
φ.
C
3
=
H
2
, we find
Introducing the Fourier transforms of the Bose operators in
straightforwardly that
H
2
]=
A
q
a
q
+
B
1+
4
J
a
+
1
ih∂a
q
/∂t
=[
a
q
,
H
]
[
a
q
,
H
1
+
−
q
+
−J
N
k
,
k
(
q
)+2
C
1
a
k
a
k
a
q
+
k
−
k
1
(
q
−
k
)+
2
J
(
k
)+
4
J
(
k
)+
4
J
,
(5
.
2
.
28)
+
C
2
3
a
k
a
+
−
k
a
k
a
q
+
k
−
k
+4
C
3
a
k
a
+
−
k
a
+
−
k
a
q
+
k
−
k
+
a
−
q
−
k
+
k
for the operator [
a
q
,
H
], which appears in the equation of motion of,
a
q
;
a
q
for instance
. When the thermal averages of terms due to
H
2
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