Environmental Engineering Reference
In-Depth Information
where J ( t ) is the angular-momentum operator in the Heisenberg pic-
ture, as in (3.2.1),
J ( t )= e iHt/h J e −iHt/h .
At thermal equilibrium, the differential cross-section can then be written
d 2 σ
dEd =
k
k
hγe 2
mc 2
2
e 2 W ( κ )
αβ
κ α κ β )
jj { 2
} j { 2
( δ αβ
gF (
κ
)
gF (
κ
)
} j
1
2 πh
dt e iωt e −i κ · ( R j R j )
×
J ( t ) J j β (0)
.
(4 . 2 . 1)
−∞
If the magnetic atoms are all identical, the form factor may be taken
outside the summation and the cross-section reduces to
hγe 2
mc 2
2
2
d 2 σ
dEd
k
k
| 2
e 2 W ( κ )
αβ (
= N
gF (
κ
)
|
( δ αβ
κ α κ β )
S
κ
) ,
αβ
(4 . 2 . 2 a )
where we have introduced the Van Hove scattering function (Van Hove
1954)
N
jj
1
2 πh
dt e iωt 1
αβ (
e −i κ · ( R j R j )
S
κ
)=
J ( t ) J j β (0)
,
−∞
(4 . 2 . 2 b )
which is (2 πh ) 1 times the Fourier transform, in space and time, of
the pair-correlation function
is added
and subtracted, the scattering function may be written as the sum of a
static and a dynamic contribution:
J ( t ) J j β (0)
. f
J
J j β
αβ
d
αβ (
αβ (
S
κ
)=
S
κ
)+
S
(
κ
) ,
(4 . 2 . 3 a )
where the static or elastic component is
N
)= δ ( ) 1
αβ (
e −i κ · ( R j R j )
S
κ
jj
J
J j β
(4 . 2 . 3 b )
and the inelastic contribution is
1
2 πh S αβ (
)= 1
π
1
αβ
d
e −βhω χ αβ (
S
(
κ
)=
κ
κ
) .
(4 . 2 . 3 c )
1
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