Environmental Engineering Reference
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where
J
jα
(
t
) is the angular-momentum operator in the Heisenberg pic-
ture, as in (3.2.1),
J
jα
(
t
)=
e
iHt/h
J
jα
e
−iHt/h
.
At thermal equilibrium, the differential cross-section can then be written
d
2
σ
dEd
Ω
=
k
k
hγe
2
mc
2
2
e
−
2
W
(
κ
)
αβ
κ
α
κ
β
)
jj
{
2
}
j
{
2
(
δ
αβ
−
gF
(
κ
)
gF
(
−
κ
)
}
j
∞
1
2
πh
dt e
iωt
e
−i
κ
·
(
R
j
−
R
j
)
×
J
jα
(
t
)
J
j
β
(0)
.
(4
.
2
.
1)
−∞
If the magnetic atoms are all identical, the form factor may be taken
outside the summation and the cross-section reduces to
hγe
2
mc
2
2
2
d
2
σ
dEd
Ω
k
k
|
2
e
−
2
W
(
κ
)
αβ
(
=
N
gF
(
κ
)
|
(
δ
αβ
−
κ
α
κ
β
)
S
κ
,ω
)
,
αβ
(4
.
2
.
2
a
)
where we have introduced the
Van Hove scattering function
(Van Hove
1954)
∞
N
jj
1
2
πh
dt e
iωt
1
αβ
(
e
−i
κ
·
(
R
j
−
R
j
)
S
κ
,ω
)=
J
jα
(
t
)
J
j
β
(0)
,
−∞
(4
.
2
.
2
b
)
which is (2
πh
)
−
1
times the Fourier transform, in space and time, of
the pair-correlation function
is added
and subtracted, the scattering function may be written as the sum of a
static and a dynamic contribution:
J
jα
(
t
)
J
j
β
(0)
. f
J
jα
J
j
β
αβ
d
αβ
(
αβ
(
S
κ
,ω
)=
S
κ
)+
S
(
κ
,ω
)
,
(4
.
2
.
3
a
)
where the static or
elastic
component is
N
)=
δ
(
hω
)
1
αβ
(
e
−i
κ
·
(
R
j
−
R
j
)
S
κ
jj
J
jα
J
j
β
(4
.
2
.
3
b
)
and the
inelastic
contribution is
1
2
πh
S
αβ
(
,ω
)=
1
π
1
αβ
d
e
−βhω
χ
αβ
(
S
(
κ
,ω
)=
κ
κ
,ω
)
.
(4
.
2
.
3
c
)
1
−
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