Environmental Engineering Reference
In-Depth Information
Within this approximation, the
γ
-strain contribution
F
γ
(
θ, φ
)tothefree
energy is
F
γ
(
θ, φ
)=
H
γ
=
c
γ
γ
1
+
γ
2
N
−
2
CA
sin
6
θ
cos 6
φ
N,
(2
.
2
.
27)
showing that these strains affect the axial-anisotropy parameters
κ
l
(
T
),
introducing effects of higher rank than
l
= 6, and that the six-fold
anisotropy in the basal plane is now
c
γ
C
2
sin
4
θ
+
4
−
2
A
2
sin
8
θ
=
−
κ
6
(
T
)=
B
6
J
(6)
I
15
/
2
[
σ
]+
2
c
γ
CA.
(2
.
2
.
28)
When both
C
and
A
are non-zero, the maximum area-conserving elon-
gation of the hexagonal planes varies between
C
+
2
A
1
,
which results in a
φ
-dependent magnetoelastic energy, and thus a contri-
bution to
κ
6
.The
γ
-strain hexagonal anisotropy decreases more slowly
(like
σ
13
at low temperatures) than the
B
6
term, as
σ
decreases, and
therefore dominates at suciently high temperatures.
The
ε
-strains may be included in a similar way. Retaining only the
lowest-rank coupling
B
ε
1
≡
|
|
and
|
C
−
2
A
|
B
(
l
=2)
ε
1
in eqn (1.4.12), we have
H
ε
=
i
2
B
ε
1
Q
2
(
J
i
)
ε
1
+
Q
−
1
(
J
i
)
ε
2
.
c
ε
(
ε
1
+
ε
2
)
−
(2
.
2
.
29)
2
Introducing the magnetostriction parameter
H
ε
of Mason (1954) (the
index
ε
should prevent any confusion with the magnetic field) by
ε
1
=
4
ε
2
=
4
H
ε
sin 2
θ
cos
φ
;
H
ε
sin 2
θ
sin
φ,
(2
.
2
.
30
a
)
we obtain within the Callen-Callen theory
2
c
ε
B
ε
1
J
(2)
I
5
/
2
[
σ
]
,
H
ε
=
(2
.
2
.
30
b
)
and the
ε
-strain contribution to the free energy
−
32
Nc
ε
H
ε
sin
2
2
θ.
F
ε
(
θ, φ
)=
(2
.
2
.
31)
The
α
-strains (1.4.10) do not influence the symmetry of the system, but
they do make a contribution, essentially proportional to
Q
2
,tothe
anisotropy, the effects of which may be derived in the same way as those
of the
γ
-and
ε
-strains. The magnetoelastic contributions to the free en-
ergy can be estimated experimentally if the elastic constants are known,
by a determination of the strains as a function of the magnetization. The
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