Environmental Engineering Reference
In-Depth Information
E = ε E b
(3.20)
Therefore, it is sufficient to calculate the balance of radiant emission and absorp-
tion of the wall, when we can adopt a gray model in estimating the radiative heat
transfer within an enclosure filled with clear gases.
3.3.1.2 Weighted-Sum-of-Gray-Gases Model
Like a solid medium, gases can absorb and emit radiative energy. Radiation from
gas typically exhibits discrete band emission/absorption in terms of wavelength,
since the interactions between molecules are relatively weak in gases. Therefore,
even if a gas is clear at a certain wavelength, it may behave nonclearly at another
wavelength. A mixed gas generally has different emission/absorption characteristics
depending on the concentration of nonclear gases. Figure 3.11 shows an example
of the distribution of absorptivity of mixed gas containing CO 2 and N 2 , 9 which varies
with gas temperature and the temperature of radiation source. Thus, it is erroneous
to neglect these features when estimating the radiative heat transfer in a furnace
filled with burned product by using a constant emissivity.
The relationship between the emissivity-path length for an unclear gas can be
expressed by
ε g = 1 - exp(- kL )
(3.21)
where k is the absorption coefficient and L is the path length of radiation. Hottel 10,11
showed that the emissivity of a real gas can be represented by the weighted sum of
gray gases, and the emissivity-path length relationship may be approximated by a
series as:
{
}
(
)
ε g
=
a
1
exp
k L
(3.22)
g n
,
n
n
where
a gn
= 1
(3.23)
,
n
where a g,n is the fractional amount of energy in the spectrum regions where the gray
gas of absorption coefficient, k n . With this expression, the absorption coefficient, k n ,
can be made independent of temperature and the temperature dependence of emis-
sivity taken by the weighting factor a g,n .
A luminous flame has a continuous spectrum emitted by the small particulates
generated during combustion processes. It means that we can assume a luminous
flame including soot particles as a gray gas. Therefore, it is convenient to approxi-
mate the variable absorptivity of combusting or burned gases, even containing soot
particles, with the weighted sum of gray gases. Johnson and Beér 12 have proposed
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