Environmental Engineering Reference
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100
Direct incident from high temperature
furnace wall
H O 19%
CO 9.5%
N 71.5%
2
80
Incident from nongray gas layer
2
2
60
40
20
0
0
2000
4000
6000
8000
cm -1
Wavelength, ν
FIGURE 2.74 Radiation characteristics of nongray gas and solid surfaces.
(
)
sinh
2
π
CD
e
D
k
=
ρ
(2.20)
(
)
(
)
ν
cosh
2
π
CD
cos
2
πν
*
D
where ρ kg/m 3 is density of the gas, e is nondimensional line intensity, D m is line
interval, C m is half line width, and ν* = |ν - ν 0 |, where ν 0 1/m is typical wave
number of an absorption band (see Table 2.4 ) . The following equations are derived
when the notion of exponential broadband model of Edwards et al. is introduced to
Equation 2.20:
e
D
A
W
=
e
ν*
W
(2.21)
π C
D
=
BP e
(2.22)
where A is nondimensional band intensity, W is a band width parameter, B is a line
broadening parameter and P e is a pressure parameter. In cases where the cosine term
of Equation 2.23 can be neglected, then the following will be true:
A
W
(
)
k
=
ρ
e
ν
*
W
tanh 2
BP
(2.23)
ν
e
i
 
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