Environmental Engineering Reference
In-Depth Information
323
.
C
12
H
10
+ H → C
12
H
9
+ H
2
2.50E+14
0.0
16000
325
.
C
12
H
9
+ C
2
H
2
→ A3 + H
3.98E+13
0.0
10100
336
.
C
10
H
8
+ H → C
10
H
7
S + H
2
2.50E+14
0.0
16000
337
.
C
10
H
8
+ H → C
10
H
7
P + H
2
2.50E+14
0.0
16000
340
.
C
8
H
6
+ H → A1YNE* + H
2
2.50E+14
0.0
16000
343
.
A1YNE* + C
2
H
2
→ C
10
H
7
S
3.98E+13
0.0
10100
358
.
C
6
H
5
+ C
2
H
2
→ C
8
H
6
+ H
3.98E+13
0.0
10100
363
.
C
7
H
7
+ H → C
7
H
8
4.81E+20
-2.1
1986
367
.
C
7
H
8
+ H → C
7
H
7
+ H
2
1.20E+14
0.0
8235
368
.
C
7
H
8
+ H → C
6
H
6
+ CH
3
1.20E+13
0.0
148
378
.
C
6
H
5
+ CH
3
→ C
7
H
7
+ H
5.00E+13
0.0
0
380
.
C
5
H
5
+ C
2
H
2
→ C
7
H
7
1.73E+17
-1.9
10231
382
.
C
4
H
4
+ C
2
H
2
→ C
6
H
6
4.47E+11
0.0
30090
383
.
C
6
H
6
+ H → C
6
H
5
+ H
2
2.50E+14
0.0
16000
388
.
C
3
H
4
+ H
2
CCCH → C
6
H
6
+ H
2.20E+11
0.0
2000
430
.
C
5
H
5
→ C
5
H
5
(L)
4.09E+47
-10.
4
54874
431
.
H
2
CCCH + C
2
H
2
→ C
5
H
5
(L)
5.62E+32
-7.3
6758
451
.
CH
2
CHCCH
2
+ O
2
→ C
4
H
4
+
HO
2
1.20E+11
0.0
0
457
.
2C
2
H
3
→ CH
2
CHCCH
2
+ H
4.00E+13
0.0
0
459
.
CH
2
CHCCH
2
+ H → C
4
H
4
+ H
2
3.00E+07
2.0
1000
466
.
C
4
H
4
+ H → H
2
CCCCH + H
2
3.00E+07
2.0
5000
479
.
H
2
CCCCH + O
2
→ CH
2
CO + HCCO
1.00E+12
0.0
0
TABLE 2.3
(CONTINUED)
Main PAH (Polycyclic Aromatic Hydrocarbons) Formation
Reactions.
k
=
AT
n
exp(-
E
/
RT
) in units of mol, cm, s, cal/mol, K
No.
Reaction
A
n
E
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