Environmental Engineering Reference
In-Depth Information
Main PAH (Polycyclic Aromatic Hydrocarbons) Formation
Reactions.
k
=
AT
n
exp(-
E
/
RT
) in units of mol, cm, s, cal/mol, K
No.
Reaction
A
n
E
5
C
10
H
7
→ INDENE* + CO
740E+11
0.0
43850
.
7
INDENE + OH → INDENE* + H
2
O
3.43E+09
1.2
-447
.
10
.
C
7
H
7
+ C
2
H
2
→ INDENE + H
3.20E+11
0.0
7000
12
.
C
10
H
7
OH + H → C
10
H
7
OH + H → C
10
H
7
O + H
2
1.15E+14
0.0
12400
13
.
C
10
H
7
OH + H → C
10
H
8
+ OH
2.23E+13
0.0
7929
19
.
C
10
H
7
S + C
2
H
2
→ A2R5 + H
3.98E+13
0.0
10100
67
.
C
10
H
7
P + C
2
H
2
→ A2YNEP + H
3.98E+13
0.0
10100
68
.
A2YNEP + H → A2YNEP*S + H
2
2.50E+14
0.0
16000
70
.
A2YNEP*S + C
2
H
2
→ A3*S1
3.98E+13
0.0
10100
82
.
A3*S1 + C
2
H
2
→ ACEPHA + H
3.98E+13
0.0
10100
84
.
C
10
H
7
S + C
6
H
6
→ FLTHN + H + H
2
4.00E+11
0.0
4000
95
.
ACEPHA → FLTHN
8.51E+12
0.0
62860
101
.
A3 + H → A3*S2 + H
2
2.50E+14
0.0
16000
102
.
A3*S2 + C
2
H
2
→ PYRENE + H
3.98E+13
0.0
10100
106
.
CPCDPYR + H → CPCDPYR*S + H
2
2.50E+14
0.0
16000
109
.
CPCDPYR*S + C
2
H
2
→ COR + H
3.98E+13
0.0
10100
155
.
FLTHN + H → FLTHN- + H
2
2.50E+14
0.0
16000
157
.
BGHIF + H → BGHIF- + H
2
3.98E+13
0.0
10100
236
.
BGHIF - + C
2
H
2
→ COR + H
3.98E+13
0.0
10100
287
.
OH + C
6
H
6
→ C
6
H
5
OH + H
8.94E+19
-2.0
13310
322
.
C
6
H
5
+ C
6
H
6
→ C
12
H
10
+ H
1.00E+12
0.0
7000
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