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3. transformation of structure and properties of anodic oxides after their
formation
4. the continuum from individual atomic events and large scale phenomena
5. solvation structure and process of silicon in solution
6. spatial distribution of reactions and evolution of surface geometry at
different scales
7. chemical bonding and stability of the atoms at different surface lattice
structures
8. difference between Si-OH and Si-F bonds in determining the chemical or
electrochemical dissolution of the silicon atom
9. physical and chemical nature of different types of surface states
10. global kinetic theories that include all the essential elements and can account
for different electrode phenomena.
The third reason is attributed to our innate interest in functional interfaces
between the man-made non-living matters and the living matters, the most important
of which is the human body. The information in the man-made world is stored and
processed electronically while that in the human body is stored and processed chemi-
cally or electrochemically. The electrochemical processes must play an important role
in enabling the technology for direct exchange of information between the two worlds.
In this regard, silicon, which is already the dominant material for processing electronic
information, seems to be a natural candidate as the electrode material on which such
interfaces could be investigated and developed. The processes to deposit organic mol-
ecules such as amino acid and proteins on silicon that can functionally bond to cells
and live tissues and the characterization for the electrochemical properties of these
silicon/bio-material interfaces should be an interesting research area in the future. 1187-1189
New interests and deeper questions, which may still be beyond the imagination
at this time, will surely continue to emerge in the future. There are more interesting
questions, on silicon electrodes to be researched now than before. In some ways, what
has been accomplished is just a preparation for the greater research challenges that lay
ahead, which must be atomistic in detail, complex in the relationships among phe-
nomena and variables, and integral in scope to relate the events at the atomic scale with
the phenomena at a macro scale.
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