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which will depend on the composition (see next), but it can range between
0.25 and 0.35 t of Co 2 .
CSA cements were developed in 1970s mainly in China (Zhang et al.,
1999; Sui and Yao, 2003) and they are/were known as 'the third series cement
of China'. These commercial materials contain 50-80 wt% of C 4 A 3 S and
30-10 wt% of C 2 S and are used mainly where rapid setting, early strength
or shrinkage compensation is required. However, structural applications were
also tested (Zhang et al., 1999 and references therein). The terminology for
yeelimite-containing cements is not uniform. Several acronyms have been
used for these cements and they are gathered in Table 18.2. In the last 15
years, the interest in CSA (and related) cements has increased due to the
potential environmental benefits of their productions. The uses of these
cements will be discussed in the next sections.
18.2 Types of calcium sulfoaluminate cements
Yeelimite-containing cements may have a very wide range of phase assemblages
that need to be clarified. These materials may be classified according to
the content of the main crystalline phase. Here, we propose to unify the
terminology used for these cements (see Table 18.2). In a later stage, the
Table 18.2 Proposed acronyms for yeelimite-containing cements. Other acronyms
in use are also given
Acronym Definition
Main phase
Second and other
phase(s)
CSA
Calcium sulfoaluminate
cement
C 4 A 3 S
C 2 S (C 4 AF, C S , CT,
...)
BCSAF
Iron-rich belite calcium
sulfoaluminate cement
C 2 S
C 4 A 3 S (C 4 AF, CT, …)
BCSAA
Aluminum-rich calcium
sulfoaluminate cement
C 2 S
C 4 A 3 S (C 12 A 7 , CA,
…)
￿ ￿ ￿ ￿ ￿ ￿
ACSA
Alite calcium sulfoaluminate
cement
C 4 A 3 S
C 3 S (C 2 S, …)
SAC
Sulfoaluminate cement
analogous to CSA
Zhang et al. (1999)
BSA
Belite sulfoaluminate
analogous to CSA
Odler (2000)
CSAC
Calcium sulfoaluminate
cement
analogous to CSA
Glasser and Zhang
(2001)
SCC
Sulfoaluminate cement clinker
analogous to CSA
Fu et al. (2003)
FAC
Ferroaluminate cement
Iron-reach CSA
Zhang et al. (1999)
SFAB
Sulfoferroaluminate belite
Iron-reach CSA
Odler (2000)
SAB
Sulphoaluminate belite
analogous to
BCSAF
Janotka et al.
(2007)
BSAF
Belite sulphoaluminate ferrite
analogous to
BCSAF
Odler (2000)
 
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