Chemistry Reference
In-Depth Information
Table 1. (Continued)
Rotational
Constants
(MHz)
Dipole
Moments
(Debye)
Frequencies
(cm
-1
)
Species
q(Bi)
q(X)
q(H)
A 89358.57
B 1397.79
C 1376.26
2114, 1784, 707, 550,
462, 241
-0.1099(As)
-0.2241(Bi)
trans
-HBi=AsH
1.625
0.3687
-0.0348
2055, 1318, 599, 450,
159, 1167i
TS2
A 110704.10
B 1253.99
C 1252.13
2165, 2158, 980, 533,
406, 169
H
2
AsBi
0.8006
0.0941
0.0482
-0.0711
1751, 1691, 713, 519,
208, 1008i
TS3
A 79666.25
B 1272.21
C 1271.08
1794, 1793, 789, 417,
398, 174
1.484
0.5462
-0.1322
-0.2070
H
2
BiAs
1920, 1740, 510, 454,
150, 1679i
TS1
A 90380.05
B 1380.90
C 1360.12
2147, 1784, 617, 515,
503, 236
-0.0770(As)
-0.2211(Bi)
cis
-HBi=AsH
1.354
0.3652
-0.0671
