Chemistry Reference
In-Depth Information
TABLE 2
(Continued)
W
(eV)
r
i
(Å)
q
2
(eVÅ)
P
0
(eVÅ)
R
K
(Å)
P
0
/3Rn
(eV)
X
(Batsanov)
Atom
Orbital
1
2
3
4
5
6
7
8
9
1.95;
1.85
Pd
5S
1
6.9026
1.325
35.377
7.2670
1.28
1.89
Ag
*
(5S
2
4d
9
)
5S
1
7.0655
1.286
37.122
6.9898
1.25
1.86
1.90
Ag
(5S
1
4d
10
)
5S
1
7.0655
1.286
26.283
6.7520
1.34
1.68
(1.66)
Cd
5S
1
7.2070
1.184
38.649
6.9898
1.38
1.69
(1.68); 1.62
1.76;
1.68
Jn
5S
2
5Ɋ
1
21.841
1.42
1.71
Sn
5P
1
7.2124
1.240
47.714
7.5313
1.40
1.79
(1.80); 1.88
R
1
= 0.5292 ǖ--orbital radius - quantum-mechanical characteristic gives the ini-
tial main value of Ɋ
E
-parameter equaled to 9.0644 eV;
R
2
= 0.375 ǖ--distance equaled to the half of the bond energy in ɇ
2
molecule. But
if hydrogen atom is bound with other atoms, its covalent radius is
≈
0.28 ǖ. Let us
explain the reason:
In accordance with Equation (13(ɚ)) Ɋ
2
= Ɋ
1
(n+1), therefore Ɋ
1
≈
9.0644 eV, Ɋ
2
≈
18.129 eV.
These are the values of possible energy criteria of stable (stationary) structures.
The dimensional characteristic 0.375 ǖ
does not satisfy them; therefore, there is a tran-
sition into the covalence radius
≈
0.28 ǖ, which provides the value of P-parameter
approximately equaled to Ɋ
2
.
From a big number of different combinations of interactions we can obtain series
with approximately equal values of P-parameters of atoms (or radicals). Such series,
by initial values of hydrogen atom, are given in Table 4 (at
< 7.5%).
First series for Ɋ
E
= 9.0644 eV--the main, initial, where ɇ, ɋ, Ɉ, and N atoms have
Ɋ
E
-parameters only of the ¿ rst electron and interactions proceed in the phase.
Second series for Ɋ'
E
= 12.792 eV is the nonrational, pathological as it more cor-
responds to the interactions in antiphase: by Equation (12(ɚ)) Ɋ''
E
= 13.596 eV.
Coef¿ cient
α
between the parameters Ɋ'
E
and Ɋ''
E
equals 6.1%, thus de¿ ning the
possibility of forming “false” bio-structures containing the molecular hydrogen ɇ
2
.
Coef¿ cient
α
α
between series I and II is 34.1%, thus con¿ rming the irrationality of
series II.
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