Bio-structural Energy Criteria of Functional States in Normal and Pathological Conditions - Progress in Organic and Physical Chemistry: Structures and Mechanisms - page 14

charged systems or heterogeneous atoms are interacting (e.g. during the formation of
valence-active radicals CH, CH 2 , CH 3 , NO 2 , etc).
In this case, P-parameters are summed up based on the principle of adding the
reverse values of P-parameters--Equations (3-5).
The difference in wave move (¨) for Ɋ-parameters can be evaluated via their rela-
tive value (

P
P

γ = ) or via relative difference of Ɋ-parameters (coef¿ cient α ), which

2
1

give an odd number at minimum of interactions:

P ¬ - 13 ; ...

222

P
P

1
2

2

n

2

γ = - At n = 0 (basic state) 12(ɚ)

-

®

P

1 1

ρ

100
90
80

70
60

50

40
30
20

10

α

5 10 15 20 25 30 35 40

FIGURE 1 Dependence of the degree of structural interactions on coefficient.

Let us point out that for stationary levels of one-dimensional harmonic oscillator
the energy of theses levels

1 ), therefore, in quantum oscillator, as opposed
to the conventional one, the least possible energy value does not equal zero.
In this model the interaction minimum does not provide the energy equaled to zero
corresponding to the principle of adding the reverse values of P-parameters.
Interference maximum, oscillation enhancing (in phase) takes place if the differ-
ence in wave move equals an even number of semi-waves:

ε = h ν (n+ 2

M =

¨=2n 2 λ n or ¨ = λ (n+1) (13)

As applicable to P-parameters, the maximum enhance of interaction in the phase cor-
responds to the interactions of similarly charged systems or systems homogeneous
by their properties and functions (e.g. between the fragments or blocks of complex
organic structures, such as CH 2 and N-NO 2 in octogene).