Environmental Engineering Reference
In-Depth Information
Table 5 Ef ciency of
gasi cation with CaO
Test #
1
2
3
Reactor temperature (
°
C)
657
690
701
S/B ratio
2.9
2.9
2.1
Gas residence time (s)
2.7
2.6
2.7
Cold gas efficiency (%)
56
70
76
Energy ef ciency (%)
32
39
47
Hydrogen production ef ciency (%)
16
23
27
Fig. 15 Thermodynamic inputs/outputs for gasi cation with CaO for maximum ef ciency case
(T = 701
°
C, S/B = 2.1,
= 2.7 s)
τ
releases 170.5 kJ/mol and added 10 % of the energy input to the system during this
particular test. This heat content can be thought of as a battery, while energy was not
inserted externally during testing, an equal amount of energy must be added during
the regeneration phase. The energy addition from the CaO reaction was added to the
energy ef
ciency equations to give a more
accurate measure of energy use during this phase. This is more useful when ana-
lyzing catalytic testing for use in a dual
ciency and hydrogen production ef
fl
fluidized bed, which is its most likely use.
4 Summary and Conclusions
Currently, the most effective method for producing hydrogen-enriched synthesis
gas from biomass is steam gasi
cation has been shown to
produce a synthetic gas with high hydrogen concentration (>70 %) under certain
cation. Steam gasi
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