Ball-milling Mechanochemical Synthesis of Coordination Bonds: Discrete Units, Polymers and Porous Materials - Ball Milling Towards Green Synthesis: Applications, Projects, Challenges - page 184

in situ and real time studies will certainly lead to important developments in
the future. The growing number of explorations of one-pot ''all-at-once''
multi-component reactions suggests that future research in metal-organic
mechanochemical synthesis will become increasingly dedicated to finding
routes to synthesizing complex products from the simplest possible react-
ants. In that light, the application of mechanochemistry to coordination
bond formation has brought the research in metal-organic materials
chemistry closer to the established traditions of synthetic organic synthesis:
of designing less expensive, more ecient, more elegant and less environ-
mentally harmful synthetic procedures.

Abbreviations
adc

acetylenedicarboxylate anion

AgOAc silver( I ) acetate

Alq 3 (8-hydroxoquinolinate)aluminium

ANA analcime topology

API active pharmaceutical ingredient

ba barbituric acid

BET Brunauer-Emmett-Teller

4,4 0 -dipyridyl bipy

bpe trans-1,2-bis(4-pyridyl)ethylene

CNacac cyanoacetylacetonate ion

cnge cyanoguanidine

Cp cyclopentadienide anion

dabco diazabicyclo[2.2.2]octane

dace 1,4-diaminocyclohexane

DMF N,N-dimethylformamide

DMSO dimethyl sulfoxide

dpn diphenyl-(2-pyridyl)phosphine

etu ethylenethiourea

FTIR Fourier-transform infrared

H 2 adc acetylenedicarboxylic acid

H 2 fum fumaric acid

H 2 salen bis(salicylidene)ethylenediamine

HCNacac cyanoacetylacetone

Him imidazole

Hina isonicotinic acid

ILAG ion- and liquid-assisted grinding

im imidazolate ion

ina isonicotinate ion

LAG liquid-assisted grinding

MOF metal-organic framework

NMR nuclear magnetic resonance

NSAID non-steroidal anti-inflammatory drug

OAc acetate ion