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Figure 7.12
(a) Dynamic nature of coordination polymers and open MOFs under
mechanochemical milling conditions: milling with a suitable liquid
phase leads to the facile transformation of different open and close-
packed zinc terephthalate frameworks materials, not observed in
analogous slurrying experiments.
95
Mechanosynthesis of rare earth
(lanthanide) ion MOF by LAG with trimesic acid leading to: (b) open
or close-packed structures depending on the choice of the grinding
liquid and (c) the formation of mixed-metal lanthanide MOFs.
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