Chemistry Reference
In-Depth Information
5.4 Summary and Outlook
In conclusion, ball milling promoted CDC and asymmetric CDC reactions
provide an e
cient method for constructing C-C bonds directly from dif-
ferent C-H bonds, a method that does not require the presence of solvents or
a long reaction time. In some of these reactions, even additional unreco-
verable metal catalysts could be avoided by exploring a unique milling
media. Furthermore, the asymmetric CDC reaction under these unusual
conditions showed a possibility for construction of optically active com-
pounds at high speed, and which could be easily performed without critical
temperature control.
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