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Fig. 8 (a) Blue lines : femtosecond-stimulated Raman scattering (FSRS) spectra of wt GFP in D 2 O,
100 fs to 1 ps following 396-nm excitation; Gaussian fits are shown as dashed red lines on
each spectrum. (b) Time dependence of vibrational structural features frequencies; they oscillate
with a period of ~280 fs. The C
N stretching, imidazolinone-ring deformation, and (C)O-D
rocking modes are in phase, and this group of modes oscillates out of phase with the C-O
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